THE DETERMINATION OF HEATING VALUES OF FUELS
2023-12-10 12:15:2 Author: hackernoon.com(查看原文) 阅读量:4 收藏

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The heating value of a fuel may be determined either by a calculation from a chemical analysis or by burning a sample in a calorimeter. In the former method the calculation should be based on an ultimate analysis, which reduces the fuel to its elementary constituents of carbon, hydrogen, oxygen, nitrogen, sulphur, ash and moisture, to secure a reasonable degree of accuracy. A proximate analysis, which determines only the percentage of moisture, fixed carbon, volatile matter and ash, without determining the ultimate composition of the volatile matter, cannot be used for computing the heat of combustion with the same degree of accuracy as an ultimate analysis, but estimates may be based on the ultimate analysis that are fairly correct. An ultimate analysis requires the services of a competent chemist, and the methods to be employed in such a determination will be found in any standard book on engineering chemistry. An ultimate analysis, while resolving the fuel into its elementary constituents, does not reveal how these may have been combined in the fuel. The manner of their combination undoubtedly has a direct effect upon their calorific value, as fuels having almost identical ultimate analyses show a difference in heating value when tested in a calorimeter. Such a difference, however, is slight, and very close approximations may be computed from the ultimate analysis. Ultimate analyses are given on both a moist and a dry fuel basis. Inasmuch as the latter is the basis generally accepted for the comparison of data, it would appear that it is the best basis on which to report such an analysis. When an analysis is given on a moist fuel basis it may be readily converted to a dry basis by dividing the percentages of the various constituents by one minus the percentage of moisture, reporting the moisture content separately.


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